Researchers from KU Leuven, led by Ivo Stassen and Rob Ameloot, have built a sensitive electronic nose with metal-organic frameworks (MOFs) to detect pesticides and nerve gas in very low concentrations.
The best-known electronic nose is the breathalyser. As drivers breathe into the device, a chemical sensor measures the amount of alcohol in their breath. This chemical reaction is then converted into an electronic signal, allowing the police officer to read off the result. Alcohol is easy to detect, because the chemical reaction is specific and the concentration of the measured gas is fairly high. But many other gases are complex mixtures of molecules in very low concentrations. Building electronic noses to detect them is thus quite a challenge.
“MOFs are like microscopic sponges,” Stassen explained. “They can absorb quite a lot of gas into their minuscule pores. We created a MOF that absorbs the phosphonates found in pesticides and nerve gases.”
The team’s detector is the most sensitive gas sensor to date and can be used to find traces of chemical weapons such as sarin or to identify the residue of pesticides on food.
Stassen claimed: “The concentrations we’re dealing with are extremely low: parts per billion – a drop of water in an Olympic swimming pool – and parts per trillion.”
Professor Rob Ameloot said that the chemical sensor can easily be integrated into existing electronic devices, by applying the MOF as a thin film over the surface of an electric circuit, for instance. Therefore, it’s fairly easy to equip a smartphone with a gas sensor for pesticides and nerve gas.
“Further research will allow us to examine other applications as well,” Prof Ameloot explained. “MOFs can measure very low concentrations, so we could use them to screen someone’s breath for diseases such as lung cancer and MS in an early stage. Or we could use the signature scent of a product to find out whether food has gone bad or to distinguish imitation wine from the original. This technology, in other words, offers a wide range of perspectives.”
Pic: The MOF used in this study consists of organic molecules (in grey and black) and metal ions (zirconium, in purple). Between these molecules are little holes that can absorb the phosphanates (in yellow). Image credit KU Leuven - Centre for Surface Chemistr
Author
Tom Austin-Morgan
Source: www.newelectronics.co.uk